Morphology,Mineralogy and Mixing of Individual Atmospheric Particles Over Kanpur (IGP): Relevance of Homogeneous Equivalent Sphere Approximation in Radiative Models

Estimation of the direct radiative forcing (DRF) by atmospheric particles is uncertain to a large extent owing to uncertainties in their morphology (shape and size), mixing states, and chemical composition. A region-specific database of the aforementioned physico-chemical properties (at individual particle level) is necessary to improve numerically-estimated optical and radiative properties. Till date, there is no detailed observation of the above mentioned properties over Kanpur in the Indo-Gangetic Plain (IGP). To fill this gap, an experiment was carried out at Kanpur (IITK; 26.52°N, 80.23°E, 142 m msl), India from April to July, 2011. Particle types broadly classified as (a) Cu-rich particles mixed with carbon and sulphur (b) dust and clays mixed with carbonaceous species (c) Fe-rich particles mixed with carbon and sulfur and (d) calcite (CaCO₃) particles aged with nitrate, were observed. The frequency distributions of aspect ratio (AR; indicator of extent of particle non-sphericity) of total 708 particles from April to June reveal that particles with aspect ratio range >1.2 to ≤1.4 were abundant throughout the experiment except during June when it was found to shift to high AR range, >1.4 to ≤1.6 (followed with another peak of AR i.e. >2 to ≤2.4) due to dust storm conditions enhancing the occurrence of more non-spherical particles over the sampling site. The spherical particles (and close to spherical shape; AR range, 1.0 to ≤1.2) were found to be <20% throughout the experiment with a minimum (11.5%) during June. Consideration of Homogeneous Equivalent Sphere Approximation (HESA) in the optical/radiative model over the study region is found to be irrelevant during the campaign.     

Energy-Efficient and Improved eWALL: e2WALL

eWALL framework, under development in the European eWALL project (project no. 610658: “eWALL for Active Long Living”) is meant for care of population with age related impairments, mild dementia and COPD. Expanded eWALL (e2WALL) is planned to be an integrated quality framework for long-term care services which will cover very different types of care: all healthcare (both preventive and rehabilitative), societal services, care for cognitive diseases, services delivered at home as well as support for caregivers as an integral part of the quality improvement process. Thus, we present e2WALL home system that would encompass installation (setup) of e2WALL in homes (flats, houses and aging homes) and their management and maintenance across Europe, starting from the partners involved in eWALL (Austria, Bulgaria, Croatia, Denmark, Former Yugoslav Republic of Macedonia, Germany, Greece, Italy, Montenegro, The Netherlands and Romania) and expanding the partnership to the most of Europe (e.g. United Kingdom, Poland, Czech Republic…). This would be a direct application of the developed e2WALL platform and should be done through a network of collaborating small-to-medium sized enterprises (SMEs), each of whom would lead the process of setting up e2WALL system and continuing to provide support services to homes in their respective country. In this way, the growth of high tech and innovative SMEs will be ensured at pan European level, which will enable growth over restricted national market and stimulate European investments in SMEs and startups. Actually, the bigger platform will enable e2WALL European Ecosystem (e4WALL), which can then expand into other non-European markets (e.g. Asia, USA) and means sustainability beyond the life of the project. e2WALL will lead to connected tech start-up hubs to the larger European business ecosystem and will contribute to increased access of country-specific and customized new product to the pan European market, which will lead to increase of employed qualified individuals. Another important focus would be creating an energy efficient environment for a new social network where registered users would provide on-demand services.     

A Note on the Effect of Microwave Heating on Iodine-Catalyzed Acetylation of Wood

The effect of microwave heating on the iodine-catalyzed acetylation of rubberwood with acetic anhydride has been investigated. Microwave radiation was used as the heating source for modifying specimens saturated with acetic anhydride in bulk solution (excess of reagent) and impregnated specimens (limited supply of anhydride). Extent of modification of wood was expressed in terms of weight percent gain (WPG) and modification was characterized using FTIR spectroscopy. In bulk solution, microwave radiations were primarily absorbed by anhydride solutions for heating purposes and a moderate WPG was obtained. However, when microwave heating was used to modify impregnated wood specimens under no excess of anhydride, a significant enhancement in degree of modification was achieved within a few minutes. The modified wood exhibited good anti-swelling efficiency.     

Nonlinear active noise control for headrest using virtual microphone control

In this paper, a feed-forward nonlinear active noise control algorithm is developed using the Filtered-S LMS (FSLMS) algorithm and virtual microphone control for an active headrest application. Virtual microphone control is implemented to attenuate noise at the ears of the headrest occupant using the physical microphones placed at remote locations. The proposed nonlinear virtual microphone control algorithm is verified in real-time in a headrest. Different nonlinear noise processes are studied and it is shown that in all cases, the FSLMS algorithm outperforms the FXLMS algorithm in controlling nonlinear primary noise at a virtual location.     

Effect of Temperature on Hydraulic Parameters of Cable-In-Conduit-Conductor of SST-1

Stable operation of superconducting magnets depend critically on the balance of heat deposition rate versus heat extraction rate by the cryo-coolant. Thus, the mass flow rate of the coolant in case of force-flow cooled superconducting magnet with Cable-In-Co-nduit-Conductor (CICC) construction becomes an important factor for optimum stability of magnets. The Toroidal and Poloidal Field magnets of Steady-state Superconducting Tokamak-1 (SST-1) is made of superconducting CICC with a void fraction of 40 %±2 %. For adequate cooling of magnets, supercritical helium at 4 bar and 4.5 K is forced-flown through the voids. Effect of temperature on mass flow rate and pressure drop in SST-1 CICC is studied in a 7 m long piece wound helically. The experimental friction factor of the CICC is also measured at different temperatures and flow rates and is compared with the standard Katheder equation and Tada equation. Also, based on the new findings obtained from the experimental results, the dimensionless Reynolds number has been slightly modified. This new number is used to propose a modified Katheder correlation for the friction factor in CICCs similar to that of SST-1.     

PCL Nanopillars Versus Nanofibers: A Contrast in Progenitor Cell Morphology,Proliferation, and Fate Determination

The role of nanotopography on the long‐term response of progenitor cells is explored using polycaprolactone (PCL) nanopillar and nanofiber surfaces seeded with plastic‐adherent rat multipotent mesenchymal stromal cells (MSCs). After 4 weeks in culture under normal expansion media conditions, MSCs cultured on nanofibers exhibit better adherence, increased proliferation, and maintain increasingly dense fibroblast‐like morphologies. In contrast, MSCs seeded on nanopillar surfaces display lowered adherence, reduced proliferation, and adopt highly elongated cellular morphologies. Immunofluorescent staining of MSCs on PCL nanopillars reveals the presence of two bone marker proteins, osteopontin and osteocalcin, providing evidence for surface induced differentiation into osteoblast‐like cells. Unlike the nanopillar topography, MSCs cultured on nanofiber and smooth PCL surfaces did not appear to undergo osteogenesis. Observed differences in cellular response to the PCL nanotopographies offer strategies to direct progenitor cell populations solely based upon submicron surface modifications. This study provides a foundation for future work exploring variations in PCL nanopillar topography with the goal of optimizing adherence and osteogenic response of MSCs.     

Performance and emission characteristics of diesel engine operated on plastic pyrolysis oil with exhaust gas recirculation

The objective of this research was to study the performance and emission characteristics of using waste plastic pyrolysis oil in diesel engine without any engine modification. The engine used in this study is a four-stroke single-cylinder naturally aspirated diesel engine (compression ignition). In the present work, the engine fuelled with blends of diesel fuel (DF) with plastic oil in the ratio of 90:10 (blend10%), 80:20 (blend20%), 70:30 (blend30%), and 50:50 (blend50%) are experimentally measured the efficiencies and emissions, analysed the performance, and compared results with that of DF.     

3D Printing technologies for drug delivery: a review

With the FDA approval of the first 3D printed tablet, Spritam®, there is now precedence set for the utilization of 3D printing for the preparation of drug delivery systems. The capabilities for dispensing low volumes with accuracy, precise spatial control and layer-by-layer assembly allow for the preparation of complex compositions and geometries. The high degree of flexibility and control with 3D printing enables the preparation of dosage forms with multiple active pharmaceutical ingredients with complex and tailored release profiles. A unique opportunity for this technology for the preparation of personalized doses to address individual patient needs. This review will highlight the 3D printing technologies being utilized for the fabrication of drug delivery systems, as well as the formulation and processing parameters for consideration. This article will also summarize the range of dosage forms that have been prepared using these technologies, specifically over the last 10 years.     

Chimie douce hydrogen production from Hg contaminated water,with desirable throughput,and simultaneous Hg-removal

Hydrogen's widespread use is fraught with many difficulties. The challenges currently are to do with safety concerns in gas storage and transportation, and low rate of production leading to non-viability of technologies at the point-of-use. Another global concern of immediate relevance involves heavy-metal ion pollution. Viable processes which can simultaneously remove and result in beneficiation of the contaminants are hitherto rarely reported. In this context we report a single-step, in situ co-reduction approach which has the dual advantage of (i) Hg contaminant removal, and (ii) room temperature hydrogen production. Hydrogen is produced via galvanic corrosion of in situ synthesized nanoaluminium amalgam. The production rate (720 mL/min for 0.5 g-Al salt) is far superior to what would be expected from the use of pure hydrides, and/or using bulk amalgams at room temperature. The method is simple, chimie douce (i.e soft chemical), hence potentially affordable, and capable of providing a means of beneficiating Hg contaminated water present in effluents from certain industries (for example, industries which uses chlor-alkali process). The in situ co-reduction approach helps in bypassing the usual rate limiting step which involves formation of an alumina passivation layer on hydrolytic material surface. Given the potential that exists in scale down and up, this approach offers a method to address the long standing challenge of point-of-use hydrogen availability.